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对丙烯酰氧基苯甲酸的合成及其铕配合物的发光性能
Synthesis of p-propylence acyl oxygen benzoic acid and its luminescence properties of Eu(PABA)(DBM)2Phen
【摘要】 用丙烯酸、氯化亚砜和对羟基苯甲酸为原料,合成了对丙烯酰氧基苯甲酸(PABA);以对丙烯酰氧基苯甲酸、二苯甲酰甲烷(DBM)为第一配体、邻菲罗啉(phen)为第二配体,合成了可聚合的Eu(PABA)(DBM)2Phen四元配合物,通过红外光谱(IR)、紫外光谱(UV)、元素分析和1H NMR对配体和配合物进行了表征。荧光光谱强度表明,对丙烯酰氧基苯甲酸(PABA)有利于Eu(PABA)(DBM)2Phen四元配合物的光致发光。
【Abstract】 P-propylene acly oxygen benzoic acid(PABA) was synthesized with propenoic acid, sulfoxide chloride and p-hydroxybenzoic acid. Polymeric Eu(PABA)(DBM)2Phen was synthesized with p-propylene acly oxygen benzoic acid(PABA), DBM as first ligand and phen as second ligands. They were characterized by IR, UV, elemental analysis and 1H NMR. Fluorescence spectrum intensity shows that para propylene acyl oxygen benzoic acid(PABA) is suitable for the photoluminescence of Eu(PABA)(DBM)2Phen quaternary complex.
【Key words】 p-propylence acyl oxygen benzoic acid(PABA); Eu(PABA)(DBM)2Phen; photoluminescence;
- 【文献出处】 贵州师范大学学报(自然科学版) ,Journal of Guizhou Normal University(Natural Sciences) , 编辑部邮箱 ,2019年05期
- 【分类号】O641.4
- 【下载频次】98