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新型高吸水聚合物凝胶型屏蔽暂堵剂MTC-1的合成及性能
Synthesis and Properties of A Novel Super-absorbent Polymer Gel Type Shielding Temporary Blocking Agent MTC-1
【摘要】 以丙烯酸(AA)、丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为原料,蒙脱土(MMT)为改性剂,过硫酸钾和无水亚硫酸氢钠为氧化还原引发体系,六亚甲基四胺(C6H12N4)为交联剂,采用水溶液聚合法合成了一种新型高吸水聚合物凝胶型屏蔽暂堵剂(MTC-1),其结构经IR表征。在最优合成条件(AM/AMPS/AA=11/7/1,m/m/m,引发剂加量0. 6 wt%,于45℃反应2. 5 h)下,MTC-1的最大吸水倍率为1006倍。岩心流动实验结果表明:MTC-1的堵水性能较高,封堵效率达到83. 72%。
【Abstract】 A novel super-absorbent polymer gel type shielding temporary blocking agent( MTC-1) was synthesized by aqueous solution polymerization using AA,AM and AMPS as materials,MMT as modification agent,K2S2O8 and NaHSO3 as initiators,C6H12N4 as crosslinker. The structure was characterized by IR. Under the optimal synthetic conditions( AM/AMPS/AA = 11/7/1,m/m/m,initiators 0. 6 wt%,reaction at 45 ℃ for 2. 5 h),the maximum water absorption ratio is 1006 times. Core flow experiment showed that MTC-1 exhibited well water shutoff performance with plugging ratio of 83. 72%.
【Key words】 polymer gel; shielding temporary plugging agent; aqueous solution polymerization; synthesis; water absorption ratio; water shutoff performance;
- 【文献出处】 合成化学 ,Chinese Journal of Synthetic Chemistry , 编辑部邮箱 ,2019年08期
- 【分类号】TE39
- 【被引频次】1
- 【下载频次】231