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La-Ti/SnO2-Sb/RuO2-Co电极制备及其处理垃圾渗滤液研究
Preparation of La-Ti/SnO2-Sb/RuO2-Co Electrode and Its Treatment of Landfill Leachate
【摘要】 以纯钛为基体材料,并以热氧化的方式制备La-Ti/SnO2-Sb/RuO2-Co电极,采用X-射线衍射仪(XRD)、扫描电子显微镜(SEM)及X-射线能量色散谱(EDS)对电极涂层表面形貌和晶体结构进行表征。采用制备的La-Ti/SnO2-Sb/RuO2-Co电极作为阳极,不锈钢为阴极,构建电化学反应器,对老龄垃圾渗滤液进行降解。结果表明在电流密度为65 mA/cm2、Cl-浓度为4 500 mg/L、初始pH=9和反应时间为6 h的最佳反应条件下,La-Ti/SnO2-Sb/RuO2-Co电极对NH3-N和COD的去除率分别达到86.5%、61%。
【Abstract】 La-Ti/SnO2-Sb/RuO2-Co electrodes were prepared by thermal oxidation using pure titanium as the matrix material. X-ray diffractometry(XRD), scanning electron microscopy(SEM) and X-ray energy dispersion were used. The surface morphology and crystal structure of the electrode coating were characterized by EDS. The prepared La-Ti/SnO2-Sb/RuO2-Co electrode was used as the anode and the stainless steel was used as the cathode to construct an electrochemical reactor to degrade the aged landfill leachate. The results show that the La-Ti/SnO2-Sb/RuO2-Co electrode under the optimal reaction conditions of current density of 65 m A/cm2,Cl-concentration of 4 500 mg/L, initial pH=9 and reaction time of 6 h. The removal rates of NH3-N and COD were 86.5% and 61%, respectively.
【Key words】 thermal oxidation; La-Ti/SnO2-Sb/RuO2-Co electrode; landfill leachate; electrochemical oxidation;
- 【文献出处】 广州化学 ,Guangzhou Chemistry , 编辑部邮箱 ,2019年04期
- 【分类号】X703
- 【网络出版时间】2019-07-02 10:36
- 【被引频次】2
- 【下载频次】157