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缅甸淡紫色翡翠的颜色成因

Color Origin of Burmese Lavender Jadeite

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【作者】 吴晓包振宇康燕韩孝朕刘学良瞿明毅

【Author】 Wu Xiao;Bao Zhenyu;Kang Yan;Han Xiaozhen;Liu Xueliang;Qu Mingyi;College of Jewelry,Shanghai Jian Qiao University;Shanghai Zhang Tie Jun Jadeite Co.,Ltd.;Instrumental Analysis Center,East China University of Science and Technology;Gemstone Testing Center,East China University of Science and Technology;

【通讯作者】 韩孝朕;

【机构】 上海建桥学院珠宝学院上海张铁军翡翠股份有限公司华东理工大学分析测试中心华东理工大学宝石检测中心

【摘要】 选取缅甸的白、淡粉紫和淡蓝紫3种颜色类型的翡翠样品,测试和分析了其元素和光吸收谱,并对其颜色成因进行了初步研究。结果表明,淡紫色翡翠样品含有少量的铁、锰和钛,而铬、钒、铜等元素的含量极低。除了Fe3+的吸收峰之外,淡粉紫色翡翠光谱中还存在峰值位于566nm处的宽吸收带,淡蓝紫色翡翠光谱中存在峰值位于534nm处的宽吸收带及长波侧625nm处的肩带,因此,淡粉紫色和淡蓝紫色翡翠分别由Mn3+和Ti3+离子致色。

【Abstract】 Three kinds of white,pale-pink purple and light-blue purple jadeite samples from Myanmar are selected for the test and analysis of elements and optical absorption spectra,and their color origins are preliminary studied.The results show that the lavender jadeite samples contain a small amount of iron,manganese and titanium,while the contents of chromium,vanadium and copper are extremely low.In addition to the absorption peak of Fe3+ ,the pale-pink purple jadeite has a broad absorption band peaking at 566 nm,and the light-blue purple jadeite has a broad absorption band peaking at 534 nm and a shoulder band at 625 nm on the long-wave side.It is inferred that the palepink purple and light-blue purple jadeite are mainly colored by Mn3+ and Ti3 +ions,respectively.

【基金】 上海建桥学院重点课程建设项目《宝石鉴定》(JXGG201715)
  • 【文献出处】 激光与光电子学进展 ,Laser & Optoelectronics Progress , 编辑部邮箱 ,2019年07期
  • 【分类号】P575;TS933
  • 【网络出版时间】2018-11-13 10:09
  • 【被引频次】7
  • 【下载频次】375
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