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百色市PM10和PM2.5中有机碳和元素碳污染特征及来源解析

Pollution Characteristics and Source Apportionment of Organic Carbon and Elemental Carbon in PM10 and PM2.5 in Baise

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【作者】 张达标陈志明莫招育梁桂云刘慧琳黄炯丽李宏姣杨俊超毛敬英林开平莫莉萍

【Author】 ZHANG Da-biao;CHEN Zhi-ming;MO Zhao-yu;LIANG Gui-yun;LIU Hui-lin;HUANG Jiong-li;LI Hong-jiao;YANG Jun-chao;MAO Jing-ying;LIN Kai-ping;MO Li-ping;Guangxi Research Institute of Environmental Protection;Key Laboratory of Environmental Change and Resources Use in Beibu Gulf, The Ministry of Education;Jinan University;Guangxi Meteorological Bureau;School of Geosciences and Engineering, Sun Yat-sen University;

【通讯作者】 莫招育;

【机构】 广西壮族自治区环境保护科学研究院北部湾环境演变与资源利用教育部重点实验室暨南大学广西气象局中山大学地球科学与工程学院

【摘要】 2015—2016年在百色市布设3个采样点采集PM10和PM2.5样品,分析其中有机碳(OC)和元素碳(EC)的含量。结果表明,PM10和PM2.5中OC、EC四季均值分别为15.0μg/m3、5.55μg/m3和11.7μg/m3、4.72μg/m3;OC与EC相关性不显著,存在不同的污染来源;OC/EC值多数>2,存在二次污染,主要来源于柴油、汽油车尾气和燃煤的排放。由总碳质气溶胶(TCA)和8个碳组分丰度分析可知,百色市碳气溶胶(CA)来源于汽车尾气、道路扬尘、燃煤的排放。二次有机碳(SOC)在OC中的占比均>75%,表明百色市大气颗粒物中OC以SOC为主,夜间污染重于昼间。

【Abstract】 PM10 and PM2.5 samples were collected at three sampling sites in Baise for analyzing the content of organic carbon(OC) and elemental carbon(EC) from 2015 to 2016. The results showed that the seasonal means of OC and EC content in PM10were 15.0 μg/m3 and 5.55 μg/m3, while in PM2.5 were 11.7 μg/m3 and 4.72 μg/m3, respectively. There was no significant correlation between OC and EC, indicating they had different pollution sources. The OC/EC ratio was over 2, indicating there was secondary pollution and the main sources were vehicle exhaust from diesel and petrol, and coal combustion. The analysis results of total carbon aerosol(TCA) and the abundance of eight carbon components showed that the carbon aerosol(CA) in Baise was mainly derived from car exhaust, road dust, and coal combustion. Secondary organic carbon(SOC) accounted for over 75% of OC, indicating SOC was dominated in OC in atmospheric particulate matter, and the pollution at night was more serious than that in daytime.

【基金】 2015年广西自然科学基金资助项目(2015GXNSFBA139203);广西科技基金资助项目(桂科AB16380292);广西高校中青年教师基础能力提升基金资助项目(2017KY0413)
  • 【文献出处】 环境监测管理与技术 ,The Administration and Technique of Environmental Monitoring , 编辑部邮箱 ,2019年02期
  • 【分类号】X513
  • 【网络出版时间】2019-03-13 09:03
  • 【被引频次】3
  • 【下载频次】256
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