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高氨氮PN/A脱氮工艺:亚硝态氮抑制后的恢复策略

HIGH-STRENGTH AMMONOIUM PN/A NITROGEN REMOVAL PROCESS: RECOVERY STRATEGY AFTER INHIBITION OF NITRITE NITROGEN

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【作者】 高远程军张亮彭永臻

【Author】 GAO Yuan;CHENG Jun;ZHANG Liang;PENG Yong-zhen;Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology, Beijing University of Technology;

【通讯作者】 彭永臻;

【机构】 北京工业大学城镇污水深度处理与资源化利用技术国家工程实验室北京市污水脱氮除磷处理与过程控制工程技术研究中心

【摘要】 高氨氮短程硝化厌氧氨氧化一体化(PN/A)工艺的稳定性受亚硝态氮影响显著。考察了高氨氮PN/A工艺受亚硝态氮短期抑制后,系统脱氮性能快速恢复的策略。稳定运行的PN/A污泥在ρ(NO-2-N)=200 mg/L条件下抑制2 h后,首先考察厌氧氨氧化菌在不同初始亚硝态氮浓度下的活性变化。此外,考察了受抑制后的PN/A工艺在不同DO浓度(0.05~1 mg/L)下的脱氮性能,结果表明:当NO-2-N浓度降低至50 mg/L以下时,厌氧氨氧化菌才明显表现出活性;受抑制后的PN/A工艺中,厌氧氨氧化菌对DO敏感度增加,恢复时系统的DO宜低于正常运行时浓度。综上所述,受NO-2-N抑制的PN/A工艺要恢复脱氮性能,宜降低亚硝态氮浓度同时控制DO浓度。在连续运行的PN/A反应器(200 L),诱发NO-2-N浓度提高到160 mg/L时,TN去除负荷从0.57下降至0.2 kg/(m3·d)。通过合理控制DO和NO-2-N浓度,系统负荷在30 d内即可恢复至原有水平,验证了以上恢复策略的可行性。

【Abstract】 The stability of partial nitrification and anammox(PN/A) process is seriously impacted by nitrite nitrogen. In this study, the strategy for rapid recovery of systematic nitrogen removal performance by high-strength ammonium PN/A process after nitrite inhibition was investigated. After inhibiting PN/A sludge of stable operation for 2 h under ρ(NO【math150 z】-N)=200 mg/L, firstly, the change in anammox activity under different nitrite nitrogen concentrations nitrogen removal performance of PN/A process under different DO concentration(0.05~1 mg/L) after nitrite inhibition were investigated and the results showed that anammox could show significant activity only when the NO-2-N concentration decreased to be lower than 50 mg/L. In addition, anammox bacteria became more sensitive to dissolved oxygen during the PN/A process after inhibition, and for recovering, the concentration of DO should be lower than that of normal operation. To sum up, to recover the nitrogen removal performance of PN/A process under nitrite inhibition, it was suggested to reduce the nitrite nitrogen concentration and control the DO concentration. In a PN/A reactor(200 L) of continuous operation, NO【math151 z】-N concentration was induced to be increased to 160 mg/L, and the total nitrogen removal rate decreased from 0.57 to 0.2 kg/(m3·d). Through reasonably controlling concentrations of DO and nitrite nitrogen, the system load recovered to the initial level in 30 d, which confirmed the feasibility of the above recovery strategy.

【关键词】 亚硝态氮积累PN/A工艺恢复策略
【Key words】 nitrite accumulationPN/Arecovery strategies
【基金】 国家自然科学基金资助项目(51578014);北京市科技计划课题(D171100001017002)
  • 【文献出处】 环境工程 ,Environmental Engineering , 编辑部邮箱 ,2019年01期
  • 【分类号】X703
  • 【被引频次】3
  • 【下载频次】342
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