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磁性CuS/γ-Fe2O3复合材料光催化处理染料废水

Photocatalytic treatment of dye wastewater by magnetic CuS/γ-Fe2O3 composites

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【作者】 钱婷婷钱露伊杜义佳陈静婷蒋茹

【Author】 QIAN Tingting;QIAN Luyi;DU Yijia;CHEN Jingting;JIANG Ru;Department of Environmental Engineering,Taizhou University;

【通讯作者】 蒋茹;

【机构】 台州学院环境工程系

【摘要】 以氯化铜、纳米γ-Fe2O3和硫脲为原材料,乙二醇为溶剂,采用溶剂热法制备了磁性CuS/γ-Fe2O3复合光催化剂。考察了该光催化剂对刚果红染料废水的处理效果。在m(CuS)∶m(γ-Fe2O3)=2∶1、刚果红初始质量浓度为10 mg/L、光催化剂投加量为0.6 g/L的最佳工艺条件下,刚果红去除率达96.51%。阴离子Cl-、NO3-及SO42-对该光催化剂的催化活性具有促进作用,其中SO42-的促进作用最显著。该光催化剂具有较好的活性稳定性,重复使用6次后刚果红去除率仍高达90.50%。

【Abstract】 Magnetic CuS/γ-Fe2O3 composite photocatalyst was prepared by solvothermal method,using copper chloride,nano γ-Fe2O3 and thiourea as raw materials,and ethylene glycol as solvent. The treatment effects of Congo Red wastewater on the photocatalyst was investigated. Under the optimum process conditions of m(CuS)∶m(γ-Fe2O3)=2∶1,initial Congo red mass concentration 10 mg/L and photocatalyst dosage 0.6 g/L,the removal rate of Congo red is 96.51%. The anions such as Cl-,NO3- and SO42- promoted the catalytic activity of the photocatalyst,wherein the promotion by SO42- was the most significant. The photocatalyst has good activity stability,and the removal rate of Congo Red is still as high as 90.50 % after reused for 6 times.

【基金】 国家自然科学基金项目(21007044,51208331);浙江省大学生科技创新活动计划暨新苗人才计划(2018R436010);台州市科技计划项目(1701bh02)
  • 【文献出处】 化工环保 ,Environmental Protection of Chemical Industry , 编辑部邮箱 ,2019年03期
  • 【分类号】X703.1
  • 【网络出版时间】2019-04-18 11:20
  • 【被引频次】8
  • 【下载频次】586
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