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O3/H2O2湿式催化氧化处理垃圾渗滤液研究

Landfill leachate treatment by O3/H2O2 wet catalytic oxidation

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【作者】 章文军章俊陈旭汤唯唯

【Author】 ZHANG Wen-jun;ZHANG Jun;CHEN XU;TANG Wei-wei;Chengtong Kaisheng Ecological Construction Co., Ltd.;Ningbo Tianhe Aquatic Ecosystems Engineering Co., Ltd.;College of Biology and Environment, University of Zhejiang Wanli;

【通讯作者】 汤唯唯;

【机构】 诚通凯胜生态建设有限公司宁波天河水生态科技股份有限公司浙江万里学院生物与环境学院

【摘要】 采用湿式催化氧化法对垃圾渗滤液进行处理,制备了活性炭载铜、铁系列催化剂,以O3/H2O2为氧化剂, COD去除率为考察指标,考察了反应工艺条件对垃圾渗滤液的处理效果。结果表明:在焙烧温度为600℃,Cu、 Fe物质的量比为3∶1时,制得的Cu-Fe/AC复合催化剂的催化剂活性相对较好;当水样体积为20 m L, H2O2投加量为0.5 mL, O3通入时间为25 min(O3流量为5 g/h),催化剂投加量为1 g时, pH值在2~4和10~12时的COD去除率较好。

【Abstract】 Wet catalytic oxidation was used to teat landfill leachate, series catalysts of copper and iron carrying activated carbon were prepared. With H2 O2/O3 as oxidant, removal rate of COD as investigation indicator,the effect of reaction condition on landfill leachate treatment was studied. The results showed that, Cu-Fe/AC composite catalyst prepared under the condition that calcinations temperature was 600 ℃, mass ratio of Cu to Fe was 3 ∶ 1, had relatively good activity. When the water sample quantity was 20 mL, the H2O2 dosage was 0.5 mL, the O3 aeration time was 25 min(flow of O3 was 5 g/h), the catalyst dosage was 1 g, the pH value was 2-4 or 10-12, good removal efficiency of COD could be obtained.

【基金】 浙江省“生物工程”一流学科开放基金项目(KF2018004);宁波市科技惠民项目(2017C50010)
  • 【文献出处】 工业用水与废水 ,Industrial Water & Wastewater , 编辑部邮箱 ,2019年03期
  • 【分类号】X703.1
  • 【被引频次】3
  • 【下载频次】233
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