节点文献

生物基N,S双掺杂荧光碳点的制备及其应用

Synthesis and application of bio-based N, S co-doped fluorescent carbon dots

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 许利娜杨小华丁海阳李梅李守海夏建陵

【Author】 XU Li-na;YANG Xiao-hua;DING Hai-yang;LI Mei;LI Shou-hai;XIA Jian-ling;Institute of Chemical Industry of Forestry Products,CAF,National Engineering Lab.for Biomass Chemical Utilization, Key Lab.of Chemical Engineering of Forest Products, National Forestry and Grassland Administration, Key Lab.of Biomass Energy and Material, Jiangsu Province, Co-Innovation Center of Efficient Processing and Utilization of Forest Resources;Institute of Forest New Technology, Chinese Academy of Forestry;

【通讯作者】 夏建陵;

【机构】 中国林业科学研究院林产化学工业研究所生物质化学利用国家工程实验室国家林业和草原局林产化学工程重点实验室江苏省生物质能源与材料重点实验室江苏省林业资源高效加工利用协同创新中心中国林业科学研究院林业新技术研究所

【摘要】 为了扩展造纸废液中的木质素磺酸钠的应用,以木质素磺酸钠和半胱氨酸为原料通过绿色的一步水热反应制备N, S双掺杂碳点,利用紫外可见光谱、荧光光谱和透射电镜等表征了碳点的光学性能、结构和对金属离子的选择性检测性能,结果表明制备的N,S双掺杂碳点可以识别Fe3+,在0.5~100μmol×L-1,Fe3+的浓度与制备的碳点的荧光猝灭强度有良好的线性关系(R2=0.995)。将制备的碳点用于实际水样,结果表明可实现水样中3价铁离子的检测。此荧光探针原料成本低廉,制备绿色简便,在检测领域和生物质资源的高附加值应用领域有着很好的应用前景。

【Abstract】 In order to expand the application of sodium lignosulfonate from pulping wastes, a green hydrothermal synthesis strategy was applied to synthesize nitrogen and sulfur co-doped carbon quantum dots using sodium lignosulfonate and L-cysteine. UV-vis spectroscopy, fluorescence spectroscopy and transmission electron microscopy were used to investigate optical properties, structure and metal ion selective detection of the carbon dots. The carbon dots can sensitively determine Fe3+ with a good linear relationship in the range of 0.5~100 μmol×L-1. The carbon dots were successfully used to measure Fe3+ concentration in environmental water samples. Furthermore, this fluorescent probe has properties of low cost, simple and green preparation,which has good potential in metal ion detection and can increase biomass added values.

【基金】 江苏省生物质能源与材料重点实验室基金(JSBEM-S-201807);中央级公益性科研院所基本科研业务费专项资金(CAFYBB2017QA016)
  • 【文献出处】 高校化学工程学报 ,Journal of Chemical Engineering of Chinese Universities , 编辑部邮箱 ,2019年04期
  • 【分类号】O657.3;O613.71;X793
  • 【被引频次】2
  • 【下载频次】685
节点文献中: 

本文链接的文献网络图示:

本文的引文网络