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碱改性杨树炭吸附水中Ni(Ⅱ)的特性研究

Study on Adsorption Characteristics of Ni(Ⅱ) in Water by Alkali Modified Poplar Charcoal

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【作者】 夏思恋王琳林少华

【Author】 XIA Silian;WANG Lin;LIN Shaohua;School of Civil Engineering, Nanjing Forestry University;

【通讯作者】 林少华;

【机构】 南京林业大学土木工程学院

【摘要】 为了提高杨树炭对水中Ni(Ⅱ)的吸附能力,采用氢氧化钠对其进行改性处理。通过杯罐实验,研究了pH对吸附效果的影响,以及吸附动力学和吸附等温线。结果表明,溶液pH值对碱改性杨树炭吸附Ni(Ⅱ)效果的影响明显,随着溶液pH从3.0提高到7.0,Ni(Ⅱ)的去除率逐渐增大。碱改性杨树炭对Ni(Ⅱ)的吸附过程符合准二级动力学规律。Freundlich等温线模型和Langmuir等温线模型均可以很好地描述碱改性杨树炭对Ni(Ⅱ)的等温吸附行为。

【Abstract】 In order to improve the adsorption capacity of Ni( Ⅱ), poplar charcoal was modified with sodium hydroxide. The effect of pH, adsorption kinetics and adsorption isotherm were investigated experimentally using batch reactor. The results showed that pH had obvious effect on adsorption capacity. The removal rate of Ni( Ⅱ) increased with the increase of pH value from 3.0 to 7.0. It was found that the adsorption kinetics of Ni( Ⅱ) by alkali modified poplar charcoal was in line with the quasi-second-order kinetic equation. Both of Freundlich isotherm model and Langmuir isotherm model could well describe the isothermal adsorption behavior of Ni( Ⅱ) on alkali modified poplar charcoal.

【关键词】 碱改性杨树炭吸附
【Key words】 modificationpoplar carbonnickeladsorption
【基金】 南京林业大学大学生创新创业训练计划项目(2018NFUSPITP768)
  • 【文献出处】 化工技术与开发 ,Technology & Development of Chemical Industry , 编辑部邮箱 ,2019年09期
  • 【分类号】X703
  • 【被引频次】1
  • 【下载频次】72
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