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新疆库车盆地富钾盐泉水化学特征与成钾显示

Hydrochemical characteristics of potassium-rich saline spring and itsimplications for sylvine deposits in the Kuqa basin, Xinjiang

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【作者】 山俊杰王明祥李建森山发寿樊启顺魏海成秦占杰袁秦张湘如李庆宽

【Author】 SHAN Junjie;WANG Mingxiang;LI Jiansen;SHAN Fashou;FAN Qishun;WEI Haicheng;QIN Zhanjie;YUAN Qin;ZHANG Xiangru;LI Qingkuan;Key Laboratory of Comprehensive and Highly Effcient Utilization of Salt Lake Resoures, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences;Key Laboratory of Salt Lake Geology and Environment of Qinghai Province;University of Chinese Academy of Sciences;

【通讯作者】 山发寿;

【机构】 中国科学院青海盐湖研究所中国科学院盐湖资源综合高效利用重点实验室青海省盐湖地质与环境重点实验室中国科学院大学

【摘要】 库车盆地古近系—新近系发育一套巨厚的膏岩盐层,钻探勘查显示,在拜城凹陷南缘5100 m深古近系库姆格列木群地层中发现钾石盐矿物。本研究采集并分析了多件盐泉水化学组成,结果显示7件盐泉水矿化度在117.7~299.4 g/L之间,钾含量在15.25~45.68 g/L之间,明显富钾,是以往报道数据(低于1 g/L)的几十倍,属于新疆首次发现。根据水化学分类,富钾盐泉水以氯化物型水为主,是Ca-Cl型卤泉水;水化学特征系数表明泉水具有高K×103/Cl和nK/nBr值、低的nMg/nCl和Br×103/Cl值(nCl-=nNa++nK+)特征。同时,盐泉水均落在25℃Na+, K+,Mg2+//Cl-,SO■-H2O五元水盐体系钾石盐相区,说明盐泉水可能溶滤了地层中的钾石盐,且受强烈构造挤压,沿地层断裂带或裂隙通道出露地表。库车盆地富钾盐泉水的发现,是新疆库车盆地含盐系地层存在固体钾盐的初步证据,对钾盐勘查的重点远景区具有重要的指示意义。

【Abstract】 One suite of thick gypsum and halite layers was discovered to occur in the Paleogene-Neogene strata, Kuqa basin, Xinjiang. Exploration and study results show that sylvite deposits developed at the depth of 5100 m in the southern margin of Baicheng depression during Paleogene. Several samples of saline spring waters from the Kuqa basin were analyzed in 2015~2016. The results indicate that seven samples have higher total dissolved solution(TDS)(117.7 to 299.4 g/L) and distinctly enriched in K+(from 15.25 to 45.68 g/L), which is several tens of time more than previous reported data(<1.0 g/L). High K+ concentrations in the spring waters are the first report in the Kuqa Basin at present. The hydrochemical classification indicates that these spring waters are dominantly chloride-type waters and belong to Ca-Cl spring brines. The ratios of hydrochemical characteristics(such as K×103/Cl, nNa/nCl, nMg/nCl, Br×103/Cl and nK/nBr) of potassium-rich spring waters show that they have high K×103/Cl and nK/nBr, low nMg/nCl and Br×103/Cl, and nCl-=nNa++nK+. Meanwhile, these potassium-rich spring waters are also plotted into sylvite phase’s area in Na+, K+, Mg2+//Cl-, SO■-H2O quinary metastable phase diagram of salt-water system at 25℃. These comparisons imply that these spring waters might leach sylvite from deep strata, and discharged and seeped along fault zones under strong tectonic compression circumstance. The discovery of these potassium-rich spring waters in the Kuqa Basin, Xinjiang demonstrates that potash deposits exist in the salt-bearing strata, and has important implications for exploration of potash deposits in this region.

【基金】 国家自然科学青年基金项目(编号41502096);中国科学院青海盐湖研究所“一三五”突破项目资助成果
  • 【文献出处】 地质学报 ,Acta Geologica Sinica , 编辑部邮箱 ,2019年05期
  • 【分类号】P619.211
  • 【被引频次】3
  • 【下载频次】272
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