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椰壳活性炭对水溶液中铀(VI)的吸附研究

Adsorption of Uranium(VI)in Aqueous Solution by Coconut Shell Activated Carbon

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【作者】 吴素强刘永何鹏

【Author】 Wu suqiang;School of Resource Environment and SafetyEngineering,University of South China;Hunan Province Engineering Technology Research Center of Uranium Tailings Decommission Treatment;

【通讯作者】 刘永;

【机构】 南华大学资源环境与安全工程学院湖南省铀尾矿库退役治理工程技术研究中心

【摘要】 以椰壳为原料制得活性炭C-1,采用KOH电镜、粉末衍射仪等仪器对C-1和C-2进行表征。结果表明,C-2含有较多的含氧官能团,会形成新的孔隙;以铀(VI)溶液为研究目标,C-1对铀的吸附量为3.01mg/g,C-2对铀的吸附容量为3.62mg/g,Lagergren准二级动力学方程和Langmuir吸附等温式能很好的描述C-1和C-2对铀(VI)的吸附。

【Abstract】 Activated carbon C-1 was prepared from coconut shell,and activated carbon C-2 was obtained by modification of C-1 by KOH activation method.The characterization methods adopted by C-1 and C-2 are mainly through infrared analyzer,scanning electron microscope,powder diffractometer and other instruments.The results show that C-2 contains more oxygen-containing functional groups and forms new pores.Taking uranium(VI)solution as the research target,the adsorption capacity of C-1 for uranium is 3.01mg/g,and the adsorption capacity of C-2 for uranium is 3.62mg/g.The Lagergren quasi-second-order kinetic equation and the Langmuir adsorption isotherm can better describe the adsorption of uranium(VI)by C-1 and C-2.

【基金】 国家自然科学基金项目(51574152,11705085);环境保护部安全监察项目资金(1620,1721);湖南省自然科学基金资助项目(2017JJ4009,2017JJ2232,2017JJ3262);湖南省科技厅中央引导地方科技发展专项资金资助项目(2017CT5006);2018年湖南省研究生科研创新基金资助项目(2018KYY154)
  • 【文献出处】 安徽农学通报 ,Anhui Agricultural Science Bulletin , 编辑部邮箱 ,2019年07期
  • 【分类号】X703
  • 【被引频次】10
  • 【下载频次】245
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