【作者】 赵雪梅；

【导师】 宋毛平；

【作者基本信息】 郑州大学 ， 有机化学， 2006， 博士

【摘要】 本论文对环金属化反应和Heck反应的研究进展作了较详细的文献总结，在此基础上，对含杂环二茂铁亚胺异环环钯化合物的合成与应用进行了以下研究。 一、含杂环二茂铁亚胺的合成与结构表征 以二茂铁氨基衍生物和相应的呋喃甲醛、噻吩甲醛、吡啶甲醛、酰基二茂铁等为原料合成了一系列新型含杂环二茂铁亚胺衍生物(Scheme 1)，并对这些化合物进行了元素分析、核磁共振、红外光谱、熔点等性质表征，其中化合物2a通过X-射线单晶衍射对其结构进行了确证。研究了不同结构的二茂铁亚胺的合成方法。更多还原

【Abstract】 In this thesis, the progress made in the studies of both the cyclometallation and Heck reaction was reviewed in detail, on the basis of which the synthese and application of heteroannular cyclopalladated ferrocenylimines involving heterocyclic ring in Heck reactions were studied in the following aspects.1. Syntheses and structural characterization of novel ferrocenylimines containing heterocyclic ringA series of novel ferrocenylimines containing heterocyclic ring were synthesized by the condensation of furaldehyde, thiophene-2-carboxaldehyde, pyridyladehyde and formylferrocene with the corresponding aminoferrocene derivatives in the presence of different solvents (Scheme 1). The products were characterized by elemental analysis, IR, NMR spectra, and the molecular structure of the compound 2a was further confirmed by X-ray crystal structure determination. Synthetic methods of different ferrocenylimines were studied in this paper.更多还原