节点文献

SrAl2O4∶Eu2+,Dy3+长余辉发光粉末表面改性及表征

Surface modification and characterization of SrAl2O4∶Eu2+,Dy3+ long afterglow luminescence powder

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 张永威朱亚楠葛明桥

【Author】 Zhang Yongwei;Zhu Yanan;Ge Mingqiao;College of Textile Science and Engineering,Jiangnan University;Key Laboratory of Eco-Textiles,Ministry of Education,Jiangnan University;

【通讯作者】 葛明桥;

【机构】 江南大学纺织科学与工程学院江南大学生态纺织教育部重点实验室

【摘要】 用KH-560硅烷偶联剂对SrAl2O4∶Eu2+,Dy3+长余辉发光粉末进行表面改性。通过测定改性样品表面的吸油值确定偶联剂添加量,并利用傅里叶红外光谱仪、扫描电子显微镜、接触角测量仪及长余辉荧光粉测试仪分别表征样品改性前后的性能变化。结果表明,硅烷偶联剂添加量为3%时,SrAl2O4∶Eu2+,Dy3+长余辉发光粉末吸油值减小至33.25%;部分偶联剂以Al-O-Si的方式接枝在长余辉发光粉末表面;改性后长余辉发光粉末疏水性提高,发光亮度略微降低。

【Abstract】 SrAl2O4∶Eu2+,Dy3+ long afterglow luminescent powders were modified by KH-560 silane coupling agent.The addition amount of coupling agent was determined by measuring the oil absorption value of the modified samples,and the changes before and after modification were characterized by fourier transmission infrared spectrometer,scanning electron microscope,contact angle measuring instrument and a long-afterglow luminescent tester.The results showed that when the addition of silane coupling agent was 3%,the oil absorption value of the powders decreased to 33.25%,and some coupling agents were grafted on the surface of the powders in the way of AlO-Si.After modification,the hydrophobicity of the powders was improved,and luminescence brightness was slightly reduced.

【基金】 江苏省自然科学基金资助项目(BK20171140);中国博士后科学基金(2018M630521)
  • 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2020年12期
  • 【分类号】TQ422
  • 【下载频次】176
节点文献中: