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激光熔覆制备Ni/TiC原位自生复合涂层及其组织形成规律研究

In-situ Composite Coating of TiC Particulate Reinforced Nickel Based Alloy Prepared by Laser Cladding and Its Microstructure Evolution

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【作者】 杨森钟敏霖刘文今

【Author】 Yang Sen,Zhong Minlin, Liu Wenjin (Department of Mechanical Engineering, Tsinghua University, Beijing 100084)

【机构】 清华大学机械工程系清华大学机械工程系 北京 100084北京 100084北京 100084

【摘要】 利用预置涂层法对三种不同成分的合金粉(Ni60A+10,15.20wt%(Ti+C))在45号钢表面进行了一系列激光表面熔覆实验。实验结果表明:利用预置涂层激光表面熔覆技术,可以在碳钢表面直接原位合成TiC颗粒增强的Ni基合金复合涂层,TiC颗粒在激光重熔过程中由石墨和钛原位反应而成。涂层与基体呈良好的冶金结合,涂层宏观质量完好,无裂纹和气孔等缺陷。涂层组织呈典型的外延生长特征,由r—奥氏体、CrB、、M23C6和TiC等相组成。原位形成的TiC颗粒与基体界面洁净,无任何附着物存在、熔覆层内TiC颗粒呈梯度分布。熔覆层内增强颗粒的数量和尺寸随涂层中添加(TiC)量的增加而增加。涂层显微硬度呈梯度分布,最大可达HV0.2850,约为基材显微硬度的3.5倍。

【Abstract】 A composite coating with TiC particles of various shapes and sizes embedded in nickel based alloy has been in - situ synthesized by laser melting a precursor mixture of nickel based alloy powder, graphite and titanium powders using a 3 kW continuous wave CO2 laser. The experiment result showed that the coating epitaxially grew from the substrate with excellent bonding between the coating and the carbon steel substrate was ensured by the strong metallurgical interface. The coating is uniform, continuous and free of pores and cracks, and about 0. 6mm thick. The microstructure of the coating is mainly composed of γ-Ni dendrite, a small amount of CrB and M23C6, and dispersed TiC particles. The volume fraction of TiC particles increase with increasing of volume fraction of Ti and C. The microhardness gradually increased from the bottom to the top of the coating layer, the maximum is HV0.2840, about 3. 5 times larger than that of the steel substrate.

【基金】 航天科技创新基金;中国博士后科学基金;清华中大博垢科学基金;清华大学985基金
  • 【文献出处】 应用激光 ,Applied Laser , 编辑部邮箱 ,2002年02期
  • 【分类号】TG174.4
  • 【被引频次】48
  • 【下载频次】293
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