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新型钙黄长石型结构环保绿色色料的制备

Preparation of Novel Environmentally Friendly Inorganic Green Pigments Based on Gehlenite-type Structure

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【作者】 熊国栋吴伯麟吴婷婷

【Author】 Xiong Guodong;Wu Bolin;Wu Tingting;Key Laboratory of New Processing Technology for Nonferrous Metals and Materials,Ministry of Education;College of Material Science and Engineering,Guilin University of Technology;Key Laboratory of New Processing Technology for Nonferrous Metals and Materials,Ministry of Education,Guangxi,Guilin;

【机构】 有色金属及材料加工新技术教育部重点实验室桂林理工大学材料科学与工程学院

【摘要】 以碳酸钙、高岭土、氧化铝为主要原料,引入Pr6O11作为发色剂,通过固相烧结反应法在1500℃下制备出一种新型绿色陶瓷色料,其呈色鲜艳,无毒无害,高温下稳定性好且制备工艺简单。通过XRD,SEM和EDS等测试手段对样品进行表征,实验结果表明:色料主要是由成分为Pr6O11与成分Ca2Al2SiO7所形成的固溶体,色料明度随Pr6O11掺入量的增加而提升。

【Abstract】 A new type of green ceramic pigment was prepared by solid state sintering reaction at 1500℃ with CaCO3,kaolin and alumina as the main raw materials.And Pr6O11 was introduced into raw materials to provide coloring ions.The color of the pigment is bright,non-toxic and harmless.The stability is good and the preparation process is simple.The samples were characterized by XRD,SEM and EDS.The results showed that the main components of the pigment were solid solution formed by Pr6O11 and Ca2Al2SiO7,and the brightness of the pigment increased with the increase of Pr6O11 content.

【关键词】 固相烧结陶瓷色料Pr6O11固溶
【Key words】 Solid state sinteringCeramic pigmentPr6O11Solid solution
【基金】 中国国家自然科学基金(项目编号:51172049);材料复合新技术国家重点实验室(武汉理工大学)开放基金资助(项目编号:2016-KF-4);广西有色金属及特色材料加工国家重点实验室培育基地(项目编号:13AA-1)
  • 【文献出处】 陶瓷 ,Ceramics , 编辑部邮箱 ,2017年03期
  • 【分类号】TQ174.4
  • 【下载频次】22
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